But Lucy Liu clearly isn't one to hold a grudge as she sat down with the comedian on Tuesday night for a light-hearted chat.
She obviously didn't let the incident in January affect her outfit choice either, looking amazing in a blue, black and white patterned silk dress.
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All's forgiven: Lucy Liu put aside being hit in
the face by a pie on her last appearance as she arrived for her
interview on Late Night With Jimmy Fallon at New York's Rockefeller
Center on Tuesday
The Elementary star was full of beans, smiling and waving to the audience as she made her way onto the stage to be greeted by the chat show host at the Rockefeller Center studio.
The 44-year-old looked stunning in her striking frock and sexy black stilettos, which featured a thin ankle strap and lace peep-toe exposing side panels.
Lucy wore her luscious long black locks down in a wavy style, while she kept her make-up fresh and natural.
In her element: The Elementary star was full of
enthusiasm as she chatted away animatedly to the comedian, looking
lovely with her long flowing black locks and picture-perfect natural
make-up
Just last month the actress opened up to TV Guide about the simmering tension between her character, Dr Joan Watson, and Jonny Lee Miller's Sherlock Holmes in the hit TV series.
'It's like going to a nude beach: it's all there, there's nothing to see, it's done. But when you go to an actual beach and people have bikinis on, there's something more sexual,' she says.
'So this is a much more interesting dynamic than actually having intercourse and a postcoital scene. This is much more energised. There are some things that have to be sacred, and right now, where we are is where we need to be.'
Having a ball: The 44-year-old was positively radiant as she laughed and smiled throughout the interview
Ready for her close-up: The star showed off her
toned legs in her pretty blue, white and black patterned silk dress,
which she paired with showstopping black stilettos with lace detail and
peep-toe design
The former Charlie's Angels star took the opportunity of being with funnyman Fallon to make her first official tweet - despite already notching up more than 17,000 followers - of the two cosying up for a selfie.
Also joining the star in the hot seat were Star Trek's Zachary Quinto and TV chef Giada De Laurentiis.
The three showed they're good sports as the took part in a fun game of Catch Phrase, much to the enjoyment of the audience.
Good sports: Lucy was joined for a game of Catch
Phrase by Star Trek star Zachary Quinto and TV chef Giada De
Laurentiis, who clearly got into the spirit of the fun activity
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